Designing in vector is much harder, as your "brush" isn't a brush per se. It can be a royal pain in the rump if you're doing it node-by-node (like in that car tut). What makes it worse is different apps use different ways to get shapes drawn, too (and not everyone uses AI). Like with 3D apps, folks train in one vector program and stay with it, so chose your path wisely.
BTW, with the OCR rendering, folks can get photo perfect and scaleable vector graphics, but it's not good for the web -- those can be some HUGE files (did one of a small tooth at low grade print quality, and the file size uncompressed was over 35mb. Thus, the primary look with few nodes and colors).
CKL